Rare Book Monthly

Articles - August - 2018 Issue

Arsenic and Old Books

C3e28b01-7ce7-4b7d-9633-b0850d0ea1be

Pretty poison.

Researchers at the University of Southern Denmark's library made a startling discovery recently about three of their 16th and 17th century books. Their covers are filled with poison. To be exact, they contain serious concentrations of arsenic. The bindings are probably more recent, likely the 19th century. Still, there are no murderous motives here, no makings of an Agatha Christie mystery. Arsenic was regularly used for a variety of purposes in those days.

 

The discovery came innocently enough. Bookbinders in past times often used paper or velum from even older books and manuscripts in their bindings. Those older books were just trash then, but today, it is often the case that the books they bound are of less interest than the older material used in the bindings. They may hold lost or unique writings that fill gaps in human knowledge. Still, the libraries or other owners who hold these books don't necessarily want them torn apart. The answer is to use modern, x-ray technologies that enable researchers to look through the covers and read the ink on the pages used in those bindings.

 

In the case of the books at the University of Southern Denmark, researchers discovered there was old parchment used in the bindings. Unfortunately, the x-rays were having a hard time reaching the elements used in writing the letters. There was a wall of green paint in the way. The x-rays revealed that the green paint was made from arsenic. It is most likely what is known as "Paris green" or "emerald green,"a substance that was used both as paint and poison. That was an unfortunate combination as it led to the use of a poisonous substance on items regularly handled by humans.

 

Among its uses as paint, Paris green was commonly used in wallpaper in the 19th century. People didn't realize its dangers. Even as they became aware of its toxic qualities, the belief remained that as long as you didn't lick your wallpaper, you would be all right. Unfortunately, it is not quite that simple. Notably in England where the pigment was commonly used and damp weather is abundant, mold can grow on the paper. It releases a toxic gas which contains the wallpaper's arsenic. Children were literally dying in their bedrooms. It is one of the reasons why people believed drier weather to be healthier. They became ill in their wallpapered homes in a damp climate, but not where dry weather prevented mold from growing.

 

Other places where the pigment was used included paintings. If you have an impressionist painting with shiny green, you should refrain from licking it. Clean with a soft, dry brush instead. Various other products regularly touched by humans, who might then put their fingers in their mouths, included items that can be worn, or toys children used for play.

 

Meanwhile, Paris green had another use. The reason it was most commonly known as Paris rather than emerald green is they used to throw it in the Paris sewers to kill the rats. People regularly kept some in their homes for that purpose. Later on, it was commonly used as an insecticide on crops. It was sprayed on apples and other fruits to prevent worms. In America, it was used to control the native Colorado potato beetle, noted for destroying potato crops. It was used in spray to kill gypsy moths invading northern forests and disease-carrying mosquitoes. It was applied to kill moths that attack tobacco plants, giving you a chance to smoke as well as eat the substance.

 

So, why was Paris green used in a bookbinding? Obviously, not for its color, since however attractive it may be, the arsenic paint was buried under the covers. Most likely, it was applied to prevent insect damage. Just as it can keep worms from boring through apples, arsenic can keep bookworms from boring through books. Now all it needs is a layer of asbestos in the covers and the books can be safe from fire damage too.

 

The Danish library will now store its poisonous books in separate boxes in a ventilated cabinet. It also plans to digitize the books so they don't have to be physically handled. Of course, the computers and monitors you use to view those digitized copies are probably laden with toxic heavy metals such as lead, cadmium, and mercury. There is no escaping the environment. You pick your poison.

 

The complete story of the discovery by Jakob Povl Holck and Kaare Lund Rasmussen of the University of Southern Denmark can be found on the website of The Conversation. 

Rare Book Monthly

  • <b>Old World Auctions (Feb 8):</b> Lot 817. Bellin's complete five-volume maritime atlas with 581 maps & plates (1764). $24,000 to $30,000.
    <b>Old World Auctions (Feb 8):</b> Lot 325. An early and important map of the Republic of Texas (1837). $11,000 to $14,000.
    <b>Old World Auctions (Feb 8):</b> Lot 45. De Bry's early map of North Pole depicting Willem Barentsz' expedition (1601). $3,500 to $4,250.
    <b>Old World Auctions (Feb 8):</b> Lot 154. Poignant map of the United States documenting lynchings (1931). $250 to $325.
    <b>Old World Auctions (Feb 8):</b> Lot 457. Extremely rare matching set of pro-German propaganda from WWI (1914). $2,000 to $2,400.
    <b>Old World Auctions (Feb 8):</b> Lot 815. Homann's world atlas featuring 110 maps in contemporary color (1751). $14,000 to $16,000.
    <b>Old World Auctions (Feb 8):</b> Lot 60. Miniature pocket globe based on Herman Moll (1785). $3,500 to $4,500.
    <b>Old World Auctions (Feb 8):</b> Lot 8. Visscher's rare carte-a-figures world map (1652). $14,000 to $16,000.
    <b>Old World Auctions (Feb 8):</b> Lot 158. Matching satirical maps of the US by McCandlish: "Ration Map" & "Bootlegger's Map" (1944). $3,000 to $4,000.
    <b>Old World Auctions (Feb 8):</b> Lot 820. One of the finest English atlases of the early 19th century (1808). $4,750 to $6,000.
    <b>Old World Auctions (Feb 8):</b> Lot 59. Important milestone in preparation for 1969 moon landing (1963). $750 to $900.
    <b>Old World Auctions (Feb 8):</b> Lot 805. Superb bible leaf with image of crucifixion of Jesus with gilt highlights (1518). $800 to $950.
  • <center><b>Potter & Potter Auctions<br>Fine Books & Manuscripts,<br>including Americana<br>February 16, 2023</b>
    <b>Potter & Potter, Feb. 16:</b> [KELMSCOTT PRESS]. CHAUCER, Geoffrey. <i>The Works…now newly imprinted.</i> Edited by F.S. Ellis. Hammersmith: Kelmscott Press, 1896. $100,000 to $125,000.
    <b>Potter & Potter, Feb. 16:</b> [EINSTEIN, Albert (1879–1955)]. –– ORLIK, Emil (1870–1932), artist. Lithograph signed (“Albert Einstein”). N.p., 1928. $10,000 to $15,000.
    <b>Potter & Potter, Feb. 16:</b> TOLKIEN, John Ronald Reuel. <i>[The Lord of the Rings trilogy:] The Fellowship of the Ring.</i> 1954. –– <i>The Two Towers.</i> 1954. –– <i>The Return of the King.</i> 1955. $10,000 to $15,000.
    <b>Potter & Potter, Feb. 16:</b> CLEMENS, Samuel Langhorne ("Mark Twain") and Charles Dudley WARNER. <i>The Gilded Age: A Tale of Today.</i> Hartford and Chicago, 1873. $6,000 to $8,000.
    <b>Potter & Potter, Feb. 16:</b> LOVECRAFT, Howard Phillips. <i>Beyond the Wall of Sleep.</i> Collected by August Derleth and Donald Wandrei. Sauk City, WI: Arkham House, 1943. $2,000 to $3,000.
  • <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
    <center><b>California International Antiquarian Book Fair<br>February 10-12, 2023<br>Pasadena Convention Center<br> abaa.org/cabookfair
  • <b><center>Swann Auction Galleries<br>View Our Record Breaking Results</b>
    <b>Swann:</b> Gideon Welles, <i>Extensive archive of personal and family papers of Lincoln’s Secretary of the Navy,</i> 1791-1914. Sold September 29 — $281,000.
    <b>Swann:</b> Charles Addams, <i>Rock Climbers,</i> cartoon for <i>The New Yorker,</i> watercolor, ink and gouache, 1954. Sold December 15 — $37,500.
    <b>Swann:</b> Charlotte Brontë, <i>Jane Eyre. An Autobiography. Edited by Currer Bell,</i> three volumes, first edition, 1847. Sold June 16, 2022 — $23,750.
    <b>Swann:</b> Geoffrey Chaucer, <i>The Workes of Geffray Chaucer Newlye Printed,</i> London, 1542. Sold October 13 — $106,250.
    <b><center>Swann Auction Galleries<br>View Our Record Breaking Results</b>
    <b>Swann:</b> Dorothea Lange, <i>Migrant Mother, Nipomo, California (Destitute pea pickers in California. Mother of seven children. Age 32),</i> silver print, 1936. Sold October 20 — $305,000.
    <b>Swann:</b> George Washington, Autograph Document Signed, with two manuscript plat maps in holograph, 1751. Sold October 27 — $37,500.
    <b>Swann:</b> Winfred Rembert, <i>Winfred Rembert and Class of 1959,</i> dye on carved & tooled leather, 1999. Sold October 6 — $233,000.
    <b>Swann:</b> M.C. Escher, <i>Relativity,</i> lithograph, 1953. Sold November 3 — $81,250.
  • <b><center>Sotheby’s<br>Original Film Posters<br>27 January - 10 February 2023</b>
    <b>Sotheby’s, Jan. 27-Feb. 10:</b> Vertigo (1958), poster, US. The ultimate poster on this classic Hitchcock title, one of three known examples. £40,000 to £60,000.
    <b>Sotheby’s, Jan. 27-Feb. 10:</b> Lawrence of Arabia (1962), roadshow poster, US. £8,000 to £12,000.
    <b>Sotheby’s, Jan. 27-Feb. 10:</b> Star Wars (1977), style C poster, printer's proof, US. £7,000 to £10,000.
    <b>Sotheby’s, Jan. 27-Feb. 10:</b> The Navigator/ La Croisiere du Navigator (1924), re-release poster (1931), French. £5,000 to £8,000.
    <b>Sotheby’s, Jan. 27-Feb. 10:</b> Bullitt (1968), special test poster, US. £3,000 to £5,000.

Article Search

Archived Articles

Ask Questions